Structure Modification and Electrochemical Properties Itensification of Molten Chloride Eletrolytes by Stimuleted Dissosition of Complex Structural Units
Dagestan State University, 367000, Russian Federation, Republic Dagestan, Makhachkala, Russia.
O.M. Shabanov, S.I. Suleymanov, L.A. Kazieva, F.O. Ismailova, ”Structure Modification and
Electrochemical Properties Itensification of Molten Chloride Eletrolytes by Stimuleted Dissosition of Complex
Structural Units”, American Research Journal of Chemical Engineering, vol 1, no. 1, pp. 1-11.
Abstract
In the molten chloride electrolytes the Wien effect and the related phenomenon the dissociation field
effect are observed. The conductivity of molten magnesium and rare earth metals chlorides and their mixtures
with the alkali metals chlorides rise with increasing electrical field intensity and strive to achieve the limiting
values in the fields of the order of 1 MV/m. The field conductance quotient achieves up to the hundreds of percent.
Under influence of completed microsecond strong electrical pulses the melts manifest the transition into a
non-equilibrium state with modification of the structure and intensification of the electrochemical properties.
As a result of prolonged structural relaxation in non-equilibrium melts, their electrochemical parameters and
structure tend to restore their equilibrium values and singularities.
